2015-07-16



Have you ever smelled jasmine? If you haven't, how could I communicate to you the sublime beauty that is engulfed in these tiny fragrant stars? To describe a scent that was never experienced is even more difficult than describing a dance choreography over the phone. Jasmine is as dewy as dawn itself, and as dark as the night. It's the sunny honeybee and at the same time a grey, dusty moth.

Jasmine is the morning sunlight through a petal, freshly opened buds of tea-like heaven, a shining evening star, and at the same time the decaying dying blossoms with brownish indole edges, the haunting fragrance of an overindulged romance that ran itself to the ground.

The complexity and emotional impact of jasmine are both beautifully portrayed in the following two poems, by Yusef Komunyakaa and Giovanni Pascoli:

Jasmine
by Yusef KomunyakaaI sit beside two women, kitty-corner
to the stage, as Elvin's sticks blur
the club into a blue fantasia.
I thought my body had forgotten the Deep
South, how I'd cross the street
if a woman like these two walked
towards me, as if a cat traversed
my path beneath the evening star.
Which one is wearing jasmine?
If my grandmothers saw me now
they'd say, Boy, the devil never sleeps.
My mind is lost among November
cotton flowers, a soft rain on my face
as Richard Davis plucks the fat notes
of chance on his upright
leaning into the future.
The blonde, the brunette--
which one is scented with jasmine?
I can hear Duke in the right hand
& Basic in the left
as the young piano player
nudges us into the past.
The trumpet's almost kissed
by enough pain. Give him a few more years,
a few more ghosts to embrace--Clifford's
shadow on the edge of the stage.
The sign says, No Talking.
Elvin's guardian angel lingers
at the top of the stairs,
counting each drop of sweat
paid in tribute. The blonde
has her eyes closed, & the brunette
is looking at me. Our bodies
sway to each riff, the jasmine
rising from a valley somewhere
in Egypt, a white moon
opening countless false mouths
of laughter. The midnight
gatherers are boys & girls
with the headlights of trucks
aimed at their backs, because
their small hands refuse to wound
the knowing scent hidden in each bloom.

Night Blooming Jasmine
by Giovanni Pascoli
And in the hour when blooms unfurl
thoughts of my loved ones come to me.
The moths of evening whirl
around the snowball tree.

Nothing now shouts or sings;
one house only whispers, then hushes.
Nestlings sleep beneath wings,
like eyes beneath their lashes.

From open calyces there flows
a ripe strawberry scent, in waves.
A lamp in the house glows.
Grasses are born on graves.

A late bee sighs, back from its tours
and no cell vacant any more.
The hen and her cheeping stars
cross their threshing floor.

All through the night the flowers flare,
scent flowing and catching the wind.
The lamp now climbs the stair,
shines from above, is dimmed...

It’s dawn: the petals, slightly worn,
close up again—each bud to brood,
in its soft, secret urn,
on some yet-nameless good.

- Poem via Poets.org

Botanical History

Jasmine is from the Oleaceae family and has originated either in either Persia, the Himalayan valley or India. Planting of jasmines (both official and sambac) were recorded as early as 3rd Century CE in China, and in the 9th Century, where it was indicated the plants came from Byzantium.But it was not until the 16th or 17th Century that it has found its way to Europe - with the Arab trade and Muslim concurs in the Middle Ages. It has been naturalized and cultivated in southern Europe as well as North Africa, and was adopted as an ornamental garden plant, where its scent can be enjoyed also in the evening after dark. Ecologically speaking, flowers like jasmine provide nectar and pollen for nocturnal insects such as moths. Their milky-white petals were also appreciated by other nocturnal creatures such as the Goth-inspirin ladies of Victorian times, who were eager to preserve their pale complexion and for them Moon Gardens were planted, with white night blooming flowers, among which was jasmine.

Traditional and Modern Extraction Methods
The Indians employed a "Sesame enfleurage"of sorts to obtain the fine perfume of jasmine. This was achieved by scattering jasmine blossoms among sesame seeds, in several batches. Once the seeds have absorbed the jasmine's fragrance, they would be pressed to produce a fragrant oil. Hot oil infusion of jasmine flowers - either J. grandiflorum or J. sambac - which then may or may not be blended into a sandalwood oil to produce the prized Attars - traditional Indian perfumes. The one from sambac is called Attar Motia; and the grandiflorum produces an Attar Chameli or Chambeli.

Enfleurage, one of the earlier modern methods (only about 250 years old) to obtain the scent of flowers that do not yield themselves to steam distillation such as jasmine, was developed in Grasse, France. With this extraction method, freshly picked flowers are arranged on trays onto which semi-solid fat is spread (usually of animal origin, with a mixture of tallow and lard achieving optimal results). This fat has to be as odourless and as insoluble in alcohol as possible. Flowers are left on these trays for extended periods of time to lend their fragrance to the fat; then, they are replaced with a new batch of flowers. It typically takes 36 batches of flowers for the desired result to be achieved before the pommade is ready for extraction. It is then washed by alcohol to produce an extrait, from which an absolute from pommade is the final result (used very much like other absolutes).
Most jasmines nowadays are produced by solvent extraction (using either hexane or previously, petroleum ether). That produces a concrete, which is treated with alcohol to separate the fragrant and precious absolute. Some of the jasmine odour stays behind within floral wax (a by-product of the solvent extraction), which is an interesting material to use in body products (body butters, soaps, etc.) and candles. I've seen references in literature to a "jasmine essential oil" that is produced from steam distillation of the absolute [4], but have never encountered it in real life, and have no idea what value such a product will hold - as many of the volatile materials in jasmine will be ruined in such high temperatures, making it a wasteful and costly raw material. I also can't see the value of this from a therapeutic standpoint - as the essence would have been already treated with synthetic solvents in the earlier stages of extraction. Traditional aromatherapists wouldn't be using either method because of their belief that trace amounts of the solvent are present in the finished product (which is highly unlikely).



Another interesting jasmine product is absolute from châssis: The exhausted flowers of enfleurage are called “châssis” (also the name of the trays in which the flowers and fat are arranged). These are further processed in hydrocarbon solvent to produce concrete from châssis, after they’ve been recovered from the solvent. Jasmine châssis is the most famous example of such a product that can still be obtained today. It provides an unusual scent, that is indole-free, and more reminiscent of orange blossom in its dark, fruity earthiness.

CO2 extraction of jasmine is also available, but only from the concrete. So again, we meet with a  similar problem - it really poses no real value as far as the trace amount concerns (or any other issues with having synthetic solvents involved in the process of extraction). I've also found the finished products both inferior to the absolute with alcohol; and also just as expensive as the jasmine absolutes on the market - if not more. It is likely to include some of the floral waxes though, so that will give a more complete representation of the flower. However, floral waxes don't dissolve in alcohol so they will be filtered out in the process of perfume-making anyway, and will only hold value in oil-based products or cosmetic formulations such as lotions, creams and butters.

Alternatives to solvent extractions are currently being tested on small-scale, for example: vegan enfleurage, and using benign solvents to produce truly organic products from start to finish. I have sampled some of these products, but have found their quality to be inconsistent so far and the price far from competitive. Considering the high cost of jasmine absolute, this makes it very difficult to consider for commercial production, even on a small scale in an artisan fragrance house. These products are mostly valuable for personal use and in aromatherapy or other holistic, natural healing models.

Traditional uses of jasmine
In aromatherapy, jasmine is used to relieve headaches, and is considered to be both intoxicating, uplifting, warming and a tonic (therefore helpful in nervous exhaustion and fatigue). Western traditions associate it with the moon and the womb. It is used to assist women in childbirth and other issues with the womb (as it is considered to bring warmth to that organ), as well as for coughs, breathing challenges, cold and catarrh.

In the emotional realm, jasmine's effect on the brain  is fascinating: it releases encephalon - a neurotransmitter which has a mild analgesic effect. Hence, the smell of jasmine alone can bring a sense of happiness and euphoria, and reduce inhibitions and act as an aphrodisiac. [2]
The Muslim doctor Al-Khindi entails in his book "Medical Formulary" a "Drug to excite intercourse: Throw in a good oil of jasmine and asafoetida and leave it for some days. Then the male organ is oiled with that oil of jasmine at the time of intercourse. The woman is excited by its contact and she experiences a strong lust". [2]

The Chinese used the J. grandiflorum flowers to treat hepatitis, liver cirrhosis and dysentery. J. sambac was used to treat conjunctivitis, dysentery, skin ulcers and tumours. Jasmine's root was used against headaches, insomnia, and to reduce pain from rheumatism or dislocated joints [4].

Beauty and Cosmetics
Jasmine's beneficial effects on the skin makes it a popular additive to skincare products, particularly facial creams where it can be enjoyed in small proportions - despite its costs. It is helpful for both dry, greasy and sensitive/irritated skin. Aside from its hefty price - the only downside for its use in creams is that due the indole causes them to get a brown discolouration. This can be avoided if using jasmine from châssis.

Varieties of Jasmine

Jasminum grandiflorum - a variety that is very similar to the J. officinale. Originates from East India, and the most commonly grown for perfumery uses. Unusually, their scent remains even after the flowers have dried - making them a good choice for tisanes and tea blends, as well as potpourri. Other names for it are Royal Jasmine, Catalonian Jasmine, Spanish Jasmine and Chambeli or Chameli (the Indian names for their attar, produced by hot oil infusion).

Jasminum officinale - with golden and silver-edged leaves, and the underneath of the flowers has a pink tint to it. It is used as the base for grafting J. grandiflorum in the South of France.

Jasminmum sambac (AKA Arabian Jasmine) - native to Arabia, and grows wild in India too. Some are single flowered, and some are double-flowered. Some varieties of J. Sambac also have multi-layered petals, similar to gardenia. Sambac jasmine is also called Sampaquita in the Philipines, Pikake in Hawaii, Tea Jasmine and Maid of Orleans.

Jasminum auriculatum, AKA Jasminum trifoliatum (AKA Tuscan Jasmine) - a variety of the Sambac jasmine that has three flowers.
Yellow varieties:
Jasminum nudiflorum (Winter jasmine) and Jasminum revolutum are fragrant yellow-flowered jasmines that original in China.

Jasminum odoratissimum is a Madeira (Portugal) variety but due to its quality of retaining its fragrance after drying, it is also grown in Formosa (Taiwan) where it is used to perfume tea. There have been successful attempts at extracting J. odoratissimum with solvent extraction, albeit with a low yield. The oil was analyzed and revealed to contain zero jasmone (the characteristic jasmine aroma), and the following constituents (compare to J. grandiflorum breakdown above):
6% Linalool
6% Linalyl acetate
1.6% Benzyl acetate
10% Indole and Methyl anthranilate
57% Diterpene or sesquiterpene alcohol

Synonyms
Arabic, Persian, Hebrew: Yasmin
Chinese: Yeh-hsi-ming
Urdu: Motia (usually found in the form of Attar Motia - Jasmine sambac distilled into sandalwood oil)
Italian: Gelsomino
French: Jasmin (silent "n")
In English, it is also referred to as Jasmine, Jasmin, Jessamine, Poet's Jasmine and Common Jasmine.

Faux Jasmines
Other so-called "jasmines" that should not be confused with the real thing:
1. Confederate Jasmine (Trachelospermum jasminoides), AKA Star Jasmine.
2. Poor Man's Jasmine (Ylang Ylang) neither looks nor smells remotely similar to jasmine, and deserves much more credit and admiration than just being a substitute for something it is not. If your nose has hard time discerning between the two - note that jasmine has significant amount of
3. Madagascar Jasmine (Stephanotis floribunda) is a tropical plant that despite its white flowers and heavenly scent, is not related to jasmine in any shape or form; but rather belongs  to the Asclepiadaceae family.
4. Jasmine nightshade (Solanum jasminoides) is a plant I'm unfamiliar with, but judging by its name, is also fragrant and reminiscent of jasmine. There are other species with the same "surname", i.e. Gardenia jasminoides.

History and Significance of Grasse Jasmine

In 2009 I've visited the rose and jasmine fields at Mul, in Le Petit Champ de Dieu valley near Grasse. This are one of the very last few growers that still grow jasmine in the region. They have 3 hectares of Jasminum grandiflorum which are the home to about 60,000 jasmine shrubs. These fields are owned by the company of Chanel and are used exclusively for No. 5 parfum extrait. These fields were originally planted by monks who were faced by a common problems: shortage of pickers. This is especially true for the jasmine, since the pickers are paid based on how much they pick - where as in rose harvest, they are paid by the hour. The other problem is finding the market for the finished product. In the olden days, most of the homes in Grasse had little jasmine fields next to them, and they only had to pick the flowers, which they then brought to a cooperative extraction plant in the city for extracting the concrete and absolute (and before that, for enfleurage process). The cooperative took care of the marketing and sales of the finished products. Now most of the jasmine fields are gone because of land development (and the issues mentioned above - which most like has caused the former jasmine growers to sell their land).

Jasmine Harvest
The Jasmine harvest happens in the heat of the summer between August and September between 6-8 weeks, and takes place between 6am-2pm, with two weighings during the day to ensure quality. The jasmine that grows in the microclimate of Grasse produces a very fine aroma - it is far lower in indole, which is higher in Indian Jasmine.

Jasmine Yield
As expected, the yield of jasmine oil varies depending on the the method used (i.e.: enfleurage or solvent extraction). You may be surprised to find out that the yield from enfleurage is much higher than from solvent extraction. Yet, in another strange turn of

What Does Jasmine Smell Like?
Jasmine is an exotic, narcotic and heady white floral note with luscious, fruity, tea-like characteristics. Generally speaking, "White Florals" are very complex, have many aspects because of the may molecules in their chemical makeup (over 100 in jasmine).
Jasmine is particularly interesting because it is simultaneously intoxicating and fresh, heavy when smelled on its own yet shines light on a composition. This is true for  jasmines, although it goes without saying that different jasmine varieties have distcintive odor characteristics (see more below). Likewise, different jasmine extractions highlight different qualities of the flower:

Jasmine grandiflorum absolute: Rich, opulent, special floral animalic notes (such as indole, skatole and paracresol). Floral, animalic, a little orange-flower like. It has a lovely, full-bodied fruity aspect that smoothes it out, giving it a creamy, delicious texture. The fruity note is somewhat reminiscent of white peach, but creamy rather than juicy. I have absolute from India, which is more earthy and indolic; and an absolute from Egypt which is lighter and smells like it has less indole and more hedione. This is how I would imagine the Grasse jasmine to be (although I have yet to encounter the absolute from this region).

Jasmine grandiflorum floral wax: Less indolic and of course less strong and complex than the absolute or concrete; but nevertheless holds a true jasmine scent that is unmistakable. My only complaint about this material is that its fragrance fades quite rapidly - so use it up within a year of purchase to prevent disappointments.

Jasmine sambac absolute: Lighter and more fruity than the grandiflorum. Tea-like (because this is the variety used for scenting the famous Chinese green tea). Very close in odour to gardenia. I love working with this note to create light, modern and exotic compositions.

Jasmine grandiflorum concrete:  An even richer form of jasmine, as it encompasses both the floral waxes and the absolute. It is rich, complex, sweet and tenacious with a creamy, smooth backdrop.
Less indolic and of course less strong and complex than the absolute or concrete; but nevertheless holds a true jasmine scent that is unmistakable. My only complaint about this material is that its fragrance fades quite rapidly - so use it up within a year of purchase to prevent disappointments.

Jasmine auriculatum absolute: The greenest of jasmine essences I've ever encountered. I am not at all fond of it, as I feel it is excessively grassy. There might be a problem with the particular specimen I have in my possession, but I can't comment as I haven't smelled others. I have used successfully in moderation to uplift green-floral compositions or to add to masculine fragrances, i.e. Gaucho.

Chemical makeup of jasmine:
Jasmine contains around 100 constituents, not of all have been identified, and many are present only in minute amount. A general idea of what jasmine absolute (from j. grandiflorum) roughly looks like this:
65% Benzyl acetate
15.5% Linalool
7.5% Linalyl acetate
6% Benzyl alcohol
2.5% Indole (dirty, fecal, animalic, also present in civet – and feces)
3% Cis-Jasmone (the heart of a jasmine, unique to jasmine alone). Please note that there is also another isomeric form of jasmone - trans-jasmone, which is synthetic and usually will be present along synthetic cis-jasmone.
0.5% Methyl anthranilate (a Concord-grape-smelling component that gives jasmine its orange flower characteristic – also present in orange flower absolute, tuberose, ylang ylang and neroli)
Other components are present at trace amounts, of which the following were identified:
Paracresol (also an animalic component, almost leathery-smelling, present in narcissus)
Farnesol
Geraniol (hint of rosy/citrus)
Skatole (gives it a hint of earthy, dung-like smell)
Phenyl acetic acid
Methyl jasmonate
Methyl dihydrojasmonate (Hedione) - which smells floral yet light spacious, and is likely the main ingredient that gives jasmine its unique ability to make any composition feel lighter and more radiant.
Cinnamyl aldehyde (which lends jasmine its warmth and hint of spiciness)

Jasmine Compounding and Reconstitution
Jasmine can be reconstituted from synthetic materials, but the imitation leaves much to be desired.
Generally speaking, cheaper raw materials are used to substitute for the authentic molecules that naturally occur in the absolute or enfleurage.

Benzyl acetate and and amyl cinnamic aldehyde (the latter at no more than 10% of the composition) provide a convincing imitation, and to that other elements of surprise may be added to create a more realistic, natural and interesting jasmine base []: maté absolute or tea absolute to bring forth the tea-like elements of jasmine; tobacco-like molecules such as

Notable jasmine-y perfumes
A La Nuit (Serge Lutens)
Drama Nuit (Parfumerie Generale)
Eau d'Hermes (Hermes) - jasmine with lemon and cumin
Emotionnelle (Parfums DelRae) - Jasmine, violet and cantaloupe
Eau Sauvage (Christian Dior) - Hedione galore (a staggering 40%) in the heart of the father of all masculines
Eclat de Jasmin (Armani Privé) - soapy yet raspy jasmine-rose riding on a well-behaved fruitchouli
Fig (Aftelier) - jasmine and fir absolute
Jasmine Rouge (Tom Ford) - realistically luxurious jasmine
Jasmin de Nuit (The Different Company)
Jasmine & White Moss (Estee Lauder) - hedione and evernyl, rebranded
Joy (Patou) - jasmine and rose
Le Parfum de Thérèse - jasmine, plum and basil sorbetto
Moon Breath - jasmine and incense
Poet's Jasmine (Ineke) - jasmine and tea
Sarassins (Serge Lutens) - scary jasmine
Samsara (Guerlain) - jasmine and sandalwood
Sampaquita (Ormonde Jayne)
Songes (Annick Goutal)
Yasmin - jasmine soliflore

[1] Arctander, Stephen "Fragrance and Flavor Materials of Natural Origin"
[2]Lawless, Julia "Aromatherapy and the Mind: The Psychological and Emotional Effects of Essential Oils", HarperCollins Canada/Thorsons, 1994
[3] Lawless, Julia "The Encyclopedia of Essential Oils: The Complete Guide to the Use of Aromatics in Aromatherapy, Herbalism, Health & Well-Being" Element Book Limited, 1992
[4] Poucher, W.a., “Perfumes, Cosmetics & Soaps with Speical reference to Synthetics Vol. 2 Being a treatise on the Production, manufacture and application of Perfumes of all types,” d. Van nostrand Company inc., 1959 (7th edition)

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